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排序方式: 共有459条查询结果,搜索用时 15 毫秒
1.
The uranium deposits in the basin of Franceville (Gabon) host the only natural fission reactors known in the world. Unique
geological conditions favoured a natural fission reaction 2 Ga ago. This was detected by anomalous isotopic compositions of
uranium and rare earth elements (REE), which are produced by the fission reaction. In total, 16 reactor zones were found.
Most of them are mined out. The reactor zone of Bangombé, is only 10–11 m below the surface. This site has been influenced
by surface weathering processes. Six drill cores have been sampled at the site of the reactor zone of Bangombé during the
course of the study and only one drill core (BAX 08) hit the core of the reactor. From these data and previous drilling campaigns,
the reactor size is estimated to be 10 cm thick, 2–3 m wide and 4–6 m long. The migration of fission products can be traced
by the anomalous isotope ratios of REE because of the fission process. The 149Sm/147Sm ratio close to the reactor zone is only 0.28 (normal: 0.92) because of the intense neutron capture of 149Sm and subsequent transmutation, whereas 147Sm is enriched by the fission reaction. Similar changes in isotopic patterns are detectable on other REE. The isotope ratios
of Sm and Nd of whole rock and fracture samples surrounding the reactor indicate that fission-genic REE migrated only a few
decimetres above and mainly below the reactor zone. Organic matter (bitumen) seems to act as a trap for fission-genic REE.
Additional REE-patterns show less intense weathering with increasing depth in the log profile and support a simple weathering
model.
Received: 26 November 1999 · Accepted: 2 May 2000 相似文献
2.
Mihoko Hoshino Mitsuyoshi Kimata Norimasa Nishida Masahiro Shimizu 《Physics and Chemistry of Minerals》2008,35(2):59-70
Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types.
Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright
zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in
unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F
0| > 4σF
0] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between
their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for
these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which
creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal,
where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified
as autoepitaxy. 相似文献
3.
4.
Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages. 相似文献
5.
6.
自然铜、铜合金矿物及其矿床形成机理新探索 总被引:8,自引:1,他引:8
描述了自然铜、铜合金矿物及其矿床形成的新机制。在岩浆及热液中,铜及铜合金可呈氢化物、羧基配合物及纳米粒子活性、迁移、富集形成自然铜矿床,或经以后的地质事件,长期、多次迁移富集,叠加形成富而大的自然铜矿床。在表生条件下,铜的硫化矿物被氧化分解,可形成亚铜的硫代硫酸盐及氯配合物,部分可形成铜的硫酸盐配合物迁移,由于硫代硫酸盐被氧化,亚铜岐化可形成高纯度的自然铜,但它易氧化形成孔雀石、蓝铜矿、赤铜矿、黑铜矿、硅孔雀石等,因此很难形成自然铜矿床。 相似文献
7.
Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy 总被引:1,自引:0,他引:1
With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO3.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO32− ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE3+ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution. 相似文献
8.
介绍了近年来华北地区宝龙等 3口井稀有气体的显著异常 ,并据其特征与井孔水位动态的关系 ,对稀有气体异常的成因进行了理论分析与实验研究。结果表明 ,水位下降 10 0mm ,岩层孔隙、裂隙中的气体体积膨胀 0 0 0 90 % (气体体积百分比 ,下同 )左右。由于地下水位大幅度下降 ,岩层孔隙压力减小 ,积聚在岩层孔隙、裂隙中的气体体积膨胀溢出 ,导致井孔地下水中稀有气体含量出现异常变化。这些异常是干扰因素所致 ,不是地震异 相似文献
9.
10.
Rare earth patterns of surface and groundwaters near big cities often show anthropogenic Gd (Gdant) anomalies in addition to geogenic Ce and Y anomalies. The Gdant anomaly is caused by very stable organic complexes, one of which is gadopentetic acid, Gd‐DTPA. Derivatives of this and similar compounds are used as contrast agents in magnetic resonance imaging (MRI) of the human blood system. The organic Gd complexes are stable enough to pass nearly unaffected through sewage treatment plants and are, thereafter, discharged into surface water systems. Water of the rapidly flowing Isarco/Eisack and Adige/Etsch rivers (Provinces of Trento and Bolzano/Bozen, NE Italy) and their tributaries show remarkable variations in anthropogenic Gd contents (Gdant). Low Gdant values are found on Monday and Tuesday, whereas high values are observed during the remaining weekdays. Reliable Gdant balances are calculated for the river system at the confluence of the Adige and its tributaries. At two places local decrease of Gdant indicates exfiltration of groundwater. It is demonstrated that Gdant can be used as a reliably conservative tracer to study the water budget in rapidly flowing alpine river systems. The studied different river waters show considerable negative Ce and positive Y anomalies. Negative Ce anomalies are caused by scavenging of Ce(III) by FeO(OH) precipitates and subsequent oxidation to CeO2. Y anomalies are attributed to less sorption of Y than REE onto particulate matter. Thus, Y moves faster than REE. Both, Ce and Y anomalies, are of geogenic origin. 相似文献